Brad Pitt and Angelina Jolie at the 84th Annual Academy Awards in Hollywood, Calif. on Feb. 26, 2012.
Lee Celano / Reuters
Former President Bill Clinton and actor Brad Pitt greet volunteers from the Clinton Global Initiative before a groundbreaking ceremony for Pitt's "Make it Right" construction project in the Lower Ninth Ward of New Orleans March 16, 2008.
Lt. Aldo Raine (Brad Pitt) and Sgt. Donny Donowitz (Eli Roth) in Quentin Tarantino's "Inglourious Basterds".
Brad Pitt, left, and Jonah Hill star in Columbia Pictures' drama Moneyball.
Jean Baptiste Lacroix / WireImage
Brad Pitt attends the 'The Tree Of Life' press conference during the 64th Annual Cannes Film Festival on May 16, 2011 in Cannes, France.
Brad Pitt in Tree of Life
Francois Duhamel / The Weinstein Co.
Brad Pitt in "Inglourious Basterds"
Brad Pitt in Quentin Tarantino's "Inglourious Basterds"
Valery Hache / AFP / Getty
Brad Pitt and Angelina Jolie arrive to attend the screening of actor and director Clint Eastwood's film Changeling at the 61st Cannes International Film Festival in 2008.
Brad Pitt and Cate Blanchett in "The Curious Case of Benjamin Button"
Brad Pitt and Cate Blanchett in The Curious Case of Benjamin Button
Merrick Morton / Paramount
Brad Pitt, left, as Benjamin Button and Cate Blanchett, right, as Daisy in The Curious Case of Benjamin Button.
Macall Pollay / Focus Features
Brad Pitt plays Chad Feldheimer in the Coen brothers new film, "Burn After Reading".
Ralf Succo / DPA / Corbis
From left: Angelina Jolie and Brad Pitt at the 'WORLD WAR Z' premiere at the Sony Center in Berlin on June 4, 2013.
Mario Anzuoni / REUTERS
Angelina Jolie and Brad Pitt pose for photographers as they arrive at the 69th annual Golden Globe Awards in Beverly Hills, Calif., on Jan. 15, 2012.
Joel Ryan / AP
Actor Brad Pitt poses for portraits during promotion for the film "The Tree of Life" at the 64th international film festival, in Cannes, southern France, Tuesday, May 17, 2011.
Kimberly French / Warner Bros.
Brad Pitt stars in "The Assassination of Jesse James by the Coward Robert Ford".
Kimblery French / Warner Bros.
Brad Pitt stars as Jesse James in The Assassination of Jesse James by the Coward Robert Ford.
VALERY HACHE / AFP / GETTY
Ooh la la Brad Pitt and Angelina Jolie add some high-voltage glamour
Murray Close / AFP / Getty
Brad Pitt and Cate Blanchett in a scene from Babel, nominated for Best Motion Picture of the Year.
Angelina Jolie with her daughter Zahara and Brad Pitt with Jolie's son Maddox in Mumbai, India, November 12, 2006.
A scene from Megamind, which stars Will Ferrell, Tina Fey and Brad Pitt
RALPH NELSON / WARNER BROS.
George Clooney, Matt Damon, and Brad Pitt in a scene from the film “Ocean’s 12